(S)-BINAP-Pd(II) Dichloride

Dichloro[(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)
CAS Number
127613-29-0
PubChem
Molecular Formula
C44H32Cl2P2Pd
Molecular Weight
800.02 g/mol
Chiral Catalysts Catalysts
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(S)-BINAP-Pd(II) dichloride is a chiral palladium catalyst used for asymmetric allylic alkylation, hydrosilylation, and enantioselective cross-coupling reactions. It serves as a versatile precursor for in-situ generation of cationic Pd(II)-BINAP species.

Applications

  • Asymmetric allylic alkylation (Tsuji-Trost)
  • Enantioselective hydrosilylation of dienes
  • Asymmetric Suzuki-Miyaura coupling
  • Asymmetric Heck reactions

Specifications

Property Value
CAS 127613-29-0
Molecular Formula C44H32Cl2P2Pd
Molecular Weight 800.02 g/mol
Purity >98%
Appearance Yellow to orange crystalline solid

Features

  • Air-stable palladium precursor
  • Broad functional group tolerance
  • Excellent enantioselectivity in allylic substitution
  • Easily activated by silver salts

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