DIPAMP

4 articles

Rhodium-Catalyzed Asymmetric Hydrogenation of Enamides and Dehydroamino Acids

Rhodium-catalyzed asymmetric hydrogenation is the most mature and industrially deployed of all enantioselective metal-catalyzed transformations. The cationic …

2026-06-25

Metal Catalysis, Science 8 tags

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Taxonomy

Privileged Chiral Bisphosphine Ligands: From DIPAMP to BINAPINE

Chiral bisphosphine ligands are the cornerstone of asymmetric hydrogenation. The evolution from DIPAMP (1970s) through CHIRAPHOS, PROPHOS, and SEGPHOS to modern variants like …

2026-02-12

Methodology, Science 8 tags

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Taxonomy

(R)-DIPAMP

(R)-DIPAMP is the enantiomeric P-stereogenic bidentate phosphine ligand, providing access to opposite enantiomers in rhodium-catalyzed asymmetric hydrogenation of dehydroamino …

0001-01-01

Chiral Ligands, Catalysts 4 tags

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(S)-DIPAMP

(S)-DIPAMP is the chiral bidentate phosphine ligand used by William Knowles in the landmark industrial synthesis of L-DOPA, the achievement recognized with the 2001 Nobel Prize in …

0001-01-01

Chiral Ligands, Catalysts 4 tags

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