Manganese

3 articles

Manganese Asymmetric Catalysis: From Mn-Salen Epoxidation to Base-Metal Pincer Catalysts

Manganese occupies a unique position in asymmetric catalysis: it is both the metal of the classic Jacobsen epoxidation catalyst (since 1990) and a leading base-metal candidate in …

2026-05-18

Metal Catalysis, Science 7 tags

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(R,R)-Jacobsen's Catalyst

(R,R)-Jacobsen’s catalyst is the enantiomeric Mn(III)-salen complex, providing access to opposite enantiomers in the asymmetric epoxidation of cis-olefins. It is essential …

0001-01-01

Chiral Catalysts, Catalysts 5 tags

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(S,S)-Jacobsen's Catalyst

(S,S)-Jacobsen’s catalyst is the chiral Mn(III)-salen complex developed by Eric Jacobsen for the asymmetric epoxidation of unfunctionalized cis-olefins. It remains one of the …

0001-01-01

Chiral Catalysts, Catalysts 5 tags

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