MonoPhos

3 articles

Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Olefins

Rhodium and ruthenium catalysts dominate asymmetric hydrogenation of functionalized olefins (enamides, enol esters), but they frequently fail on unfunctionalized, tri-substituted, …

2026-05-10

Metal Catalysis, Science 7 tags

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Taxonomy

Phosphoramidite Ligands: MonoPhos and the Modular Approach to Asymmetric Catalysis

Phosphoramidite ligands, introduced by Feringa and de Vries in the late 1990s, are a modular class of monodentate chiral phosphorus ligands derived from BINOL and secondary amines. …

2026-02-05

Methodology, Science 7 tags

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Taxonomy

(S)-MonoPhos

(S)-MonoPhos is a chiral monodentate phosphoramidite ligand developed by Feringa and de Vries. Derived from (S)-BINOL, it forms highly enantioselective rhodium complexes for …

0001-01-01

Chiral Ligands, Catalysts 5 tags

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