Palladium

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Palladium-Catalyzed Enantioselective Cross-Coupling: Atroposelective Suzuki and Asymmetric Heck

While most palladium cross-coupling uses achiral phosphines, a growing family of enantioselective Pd-catalyzed reactions uses chiral diphosphines to construct stereocenters and …

2026-06-12

Metal Catalysis, Science 8 tags

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Buchwald Biaryl Phosphine Ligands: Revolutionizing Palladium-Catalyzed Cross-Coupling

Palladium-catalyzed cross-coupling has been transformed over the past two decades by Stephen Buchwald’s development of electron-rich, sterically demanding biaryl phosphine …

2026-05-15

Methodology, Science 7 tags

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NHC-Catalyzed Organic Transformations with IMes and IPr Precatalysts

N-heterocyclic carbenes (NHCs) have, since the late 1990s, become indispensable ligands in transition-metal catalysis. The two most widely used NHCs — IMes …

2026-05-08

Methodology, Science 7 tags

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Trost DACH-Phenyl Ligand in Asymmetric Allylic Alkylation: API Synthesis Applications

The Trost modular ligand family, based on trans-1,2-diaminocyclohexane (DACH) backbone with tartaric-acid-derived bridging groups, is the privileged scaffold for …

2026-04-30

Applications, Industry 6 tags

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Asymmetric C–H Activation with Chiral Palladium and Rhodium Catalysts

Asymmetric C–H activation — the enantioselective functionalization of an unactivated C–H bond — is one of the most active frontiers in organic synthesis. By converting a C–H bond …

2026-04-12

Metal Catalysis, Science 7 tags

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(R,R)-DACH-Phenyl Trost Ligand

(R,R)-DACH-phenyl Trost ligand is the privileged chiral diphosphine ligand developed by Barry Trost, built on a trans-1,2-diaminocyclohexane (DACH) backbone with …

0001-01-01

Chiral Ligands, Catalysts 5 tags

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(S,S)-DACH-Phenyl Trost Ligand

(S,S)-DACH-phenyl Trost ligand is the enantiomeric form of the privileged Trost diphosphine ligand, providing complementary stereochemical outcomes in palladium-catalyzed …

0001-01-01

Chiral Ligands, Catalysts 5 tags

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(S)-BINAP-Pd(II) Dichloride

(S)-BINAP-Pd(II) dichloride is a chiral palladium catalyst used for asymmetric allylic alkylation, hydrosilylation, and enantioselective cross-coupling reactions. It serves as a …

0001-01-01

Chiral Catalysts, Catalysts 4 tags

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