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rhodium asymmetric hydrogenation enamide dehydroamino acid DIPAMP BINAPINE SEGPHOS chiral ruthenium BINAP diamine aryl ketone DPEN DAIPEN Noyori asymmetric transfer hydrogenation TsDPEN ketone reduction palladium asymmetric cross-coupling Suzuki Heck atroposelective ketone CBS oxazaborolidine borane Corey copper conjugate addition 1,4-addition quaternary center phosphoramidite BOX chiral phosphoric acid TRIP BINOL organocatalysis Brønsted acid titanium TADDOL Lewis acid Diels-Alder carbonyl-ene cyanation metathesis Grubbs Hoveyda-Grubbs ring-closing cross-metathesis manganese Mn-salen Jacobsen base metal epoxidation pincer Buchwald biaryl phosphine SPhos XPhos RuPhos iridium unfunctionalized olefin MonoPhos Crabtree NHC IMes IPr carbene Trost DACH allylic alkylation API nickel Negishi spiro SPINOL SIPHOS Zhou Qi-Lin rigid backbone iron cobalt sustainable hydroformylation Xantphos Biphephos oxo process industrial C-H activation directing group olefin hydroboration hydrosilylation MacMillan imidazolidinone SOMO photoredox dual catalysis radical visible light cinchona alkaloid phase-transfer cinchonidine quinine Jorgensen Hayashi diarylprolinol enamine iminium BINAL-H chiral hydride reduction bisoxazoline cycloaddition t-Bu-BOX DIOP hydrogenation bisphosphine CHIRAPHOS PROPHOS evolution allylic substitution green chemistry flow chemistry ionic liquids proline DMAP sustainability process catalysis custom synthesis CDMO manufacturing

Allylic Alkylation

3 articles

Taxonomy

Trost DACH-Phenyl Ligand in Asymmetric Allylic Alkylation: API Synthesis Applications

The Trost modular ligand family, based on trans-1,2-diaminocyclohexane (DACH) backbone with tartaric-acid-derived bridging groups, is the privileged scaffold for …

2026-04-30
Applications, Industry 6 tags
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Taxonomy

(R,R)-DACH-Phenyl Trost Ligand

(R,R)-DACH-phenyl Trost ligand is the privileged chiral diphosphine ligand developed by Barry Trost, built on a trans-1,2-diaminocyclohexane (DACH) backbone with …

0001-01-01
Chiral Ligands, Catalysts 5 tags
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Taxonomy

(S,S)-DACH-Phenyl Trost Ligand

(S,S)-DACH-phenyl Trost ligand is the enantiomeric form of the privileged Trost diphosphine ligand, providing complementary stereochemical outcomes in palladium-catalyzed …

0001-01-01
Chiral Ligands, Catalysts 5 tags
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