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rhodium asymmetric hydrogenation enamide dehydroamino acid DIPAMP BINAPINE SEGPHOS chiral ruthenium BINAP diamine aryl ketone DPEN DAIPEN Noyori asymmetric transfer hydrogenation TsDPEN ketone reduction palladium asymmetric cross-coupling Suzuki Heck atroposelective ketone CBS oxazaborolidine borane Corey copper conjugate addition 1,4-addition quaternary center phosphoramidite BOX chiral phosphoric acid TRIP BINOL organocatalysis Brønsted acid titanium TADDOL Lewis acid Diels-Alder carbonyl-ene cyanation metathesis Grubbs Hoveyda-Grubbs ring-closing cross-metathesis manganese Mn-salen Jacobsen base metal epoxidation pincer Buchwald biaryl phosphine SPhos XPhos RuPhos iridium unfunctionalized olefin MonoPhos Crabtree NHC IMes IPr carbene Trost DACH allylic alkylation API nickel Negishi spiro SPINOL SIPHOS Zhou Qi-Lin rigid backbone iron cobalt sustainable hydroformylation Xantphos Biphephos oxo process industrial C-H activation directing group olefin hydroboration hydrosilylation MacMillan imidazolidinone SOMO photoredox dual catalysis radical visible light cinchona alkaloid phase-transfer cinchonidine quinine Jorgensen Hayashi diarylprolinol enamine iminium BINAL-H chiral hydride reduction bisoxazoline cycloaddition t-Bu-BOX DIOP hydrogenation bisphosphine CHIRAPHOS PROPHOS evolution allylic substitution green chemistry flow chemistry ionic liquids proline DMAP sustainability process catalysis custom synthesis CDMO manufacturing

Catalyst Ligands

5 articles

Taxonomy

Biphephos

Biphephos is the industrial benchmark bisphosphite ligand developed by Union Carbide. It enables highly regioselective rhodium-catalyzed hydroformylation of internal and terminal …

0001-01-01
Catalyst Ligands, Catalysts 4 tags
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Taxonomy

RuPhos

RuPhos (2-dicyclohexylphosphino-2’,6’-diisopropoxy-1,1’-biphenyl) is a Buchwald biaryl phosphine ligand optimized for C–N cross-coupling. It excels at coupling …

0001-01-01
Catalyst Ligands, Catalysts 4 tags
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Taxonomy

SPhos

SPhos (2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl) is the iconic Buchwald biaryl phosphine ligand. Its electron-rich and sterically demanding character enables …

0001-01-01
Catalyst Ligands, Catalysts 4 tags
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Taxonomy

Xantphos

Xantphos (4,5-bis(diphenylphosphino)-9,9-dimethylxanthene) is the privileged wide bite-angle (≈108°) bidentate phosphine ligand developed by van Leeuwen. It is the industry …

0001-01-01
Catalyst Ligands, Catalysts 4 tags
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Taxonomy

XPhos

XPhos (2-dicyclohexylphosphino-2’,4’,6’-triisopropylbiphenyl) is a privileged Buchwald biaryl phosphine ligand. The bulky, electron-rich character enables highly …

0001-01-01
Catalyst Ligands, Catalysts 4 tags
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